Yellowing in transparent silicone tubing has several causes, and the dominant one in most service environments is thermo-oxidative aging: sustained heat exposure causes oxidation of the polymer chains, generating chromophoric groups that absorb visible light. In peroxide-cured tubing specifically, decomposition residuals from the vulcanizing agent — such as organic acids — are a direct contributor to yellowing, as they remain in the material matrix after curing and react with time and heat. UV exposure triggers photooxidation through a separate mechanism, while contact with nitrogen oxides, ozone, or certain chemicals in the environment can initiate surface discoloration independently.